ISSN:1000-8365 CN:61-1134/TG
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Effect of Heating Rate on Hydride Precipitation in Zirconium Alloys
Author of the article:CHENG Shaoyang1, YAN Mengyuan1, HUI Boning1,2, CHEN Biao2, LI Jinshan2
Author's Workplace:1. Xi'an Western Energy Material Technologies Co., Ltd., Xi'an 710299, China; 2. State Key Laboratory of SolidificationProcessing, Northwestern Polytechnical University, Xi'an 710072, China
Key Words: zirconium alloys; hydride; heating rate; reorientation
Abstract:
Zirconium alloys are widely used as fuel cladding in light water reactors because of their optimal combination ofmechanical strength, corrosion resistance, and low neutron absorption cross-section. During operation, cladding inevitablyabsorbs hydrogen from the high-temperature coolant. Conventionally, hydride precipitates exhibit a circumferentialorientation under stress-free conditions, and reorientation into a radial morphology is traditionally attributed to sustainedtensile hoop stress. Here, it is demonstrated that pronounced hydride reorientation can occur under stress-free conditions,triggered solely by rapid thermal transients. The experimental results reveal that at a heating rate of 20 ℃/min, a localized,radially oriented hydride aggregation zone—resembling a “sunspot”—emerges on the outer cladding surface. Mechanisticanalysis indicates that rapid heating establishes a steep through-thickness temperature gradient, which, under deformationcompatibility, forces the expanding outer wall to be constrained by the inner wall and consequently drives a dynamiccircumferential tensile stress gradient. This transient gradient drives solute hydrogen toward regions of higher tensile stressvia uphill diffusion and triggers rapid precipitation in the supersaturated matrix, preferentially aligning hydridesperpendicular to the principal tensile axis.