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Al-Cu-Mn-Fe-Ag-Zr 合金的微观组织与 室温和高温性能研究
Study of the Microstructure and Room- and High-Temperature Properties of an Al-Cu-Mn-Fe-Ag-Zr Alloy
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- DOI:
- 作者:
- 刘敬彬,栗梦玉,胡静怡,苏宏福,高 通,刘相法
LIU Jingbin, LI Mengyu, HU Jingyi, SU Hongfu, GAO Tong, LIU Xiangfa
- 作者单位:
- 山东大学 材料液固结构演变与加工教育部重点实验室,山东 济南 250061
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, Shandong University, Jinan 250061, China
- 关键词:
- Al-Cu-Mn-Fe-Ag-Zr 合金; Al-Cu 铸造合金;耐热性能; T6 热处理
Al-Cu-Mn-Fe-Ag-Zr alloy; Al-Cu casting alloys; heat resistance; T6 heat treatment
- 摘要:
- Al-Cu 合金具有低密度、耐热性好和潜在的高温稳定性等优点,广泛应用于汽车和航空航天等领域。 为提高 Al-Cu 基铸造合金的耐热性能,本文制备了质量分数为 Al-4%Cu-0.5%Mn-0.1%Fe-0.4%Ag-0.3%Zr( 简称 AC) 的合金。采用 OM 和 SEM 分析了合金的微观形貌及化学成分,采用 XRD 分析了合金的物相结构,采用 EBSD 研究了晶粒形态与尺寸分布,采用 TEM 分析了合金在时效处理后的微观组织和析出相形态,采用高低温拉伸试验机进行了室温和高温力学性能测试。 结果表明, AC 合金在铸造过程中形成的金属间化合物主要包括 Al 2 Cu 和 Al 7 Cu 2 Fe ,其中, Al 2 Cu 相在固溶处理后溶入基体中,并在时效处理后重新沉淀为 θ′ 相,成为主要的强化相。 此外,经 T6 热处理后,合金中还包含着T Mn (Al 20 Cu 2 Mn 3 ) 相, Ag 元素固溶于铝基体中,而 Zr 元素则使得合金析出 L1 2 -Al 3 Zr 纳米相,其与 θ′ 相存在位向关系。 测试了合金在室温和高温 (200 、 300 和 400 ℃) 下的拉伸性能,对应屈服强度可分别达 236 、 155 、 129 和 61 MPa 。Al-Cu alloys are widely used in automotive and aerospace applications due to their low density, good heat resistance and potential high-temperature stability. To improve the heat resistance of Al-Cu casting alloys, an alloy with a mass fraction of Al-4%Cu-0.5%Mn-0.1%Fe-0.4%Ag-0.3%Zr (AC) was prepared. The microscopic morphology and chemical composition of the alloy were analysed by OM and SEM, the phase structure was analysed by XRD, the grain morphology and size distribution were investigated by EBSD, the microstructural details and precipitated phases after aging treatment were analysed by TEM, and the mechanical properties at room temperature and high temperature were tested by a tensile testing machine. The results show that the intermetallic compounds that formed during the casting process of the AC alloy include Al 2 Cu and Al 7 Cu 2 Fe. The Al 2 Cu phase dissolves into the matrix after solid solution treatment and reprecipitates as the θ′ phase after aging treatment, acting as the main strengthening phase. After T6 heat treatment, the alloy also contains the T Mn (Al 20 Cu 2 Mn 3 ) phase. Moreover, Ag dissolves in the Al matrix, and the addition of Zr leads to the precipitation of the L1 2 -Al 3 Zr nanophase, which coincides with the location of the θ′ precipitated phase. The tensile properties of the alloys were tested at room and high temperatures (200, 300 and 400 ℃), and the yield strengths are 236, 155, 129 and 61 MPa, respectively.