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电弧熔炼与热挤压复合工艺对Cu-15Sn-0.3Ti 合金组织及性能的影响
Influence of Arc Melting and Hot Extrusion Composites on the Microstructure and Properties of Cu-15Sn-0.3Ti Alloy
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- DOI:
- 作者:
- 白云飞1,邹军涛1,孙利星1,2,张 喆1,王宇轩1
BAI Yunfei1, ZOU Juntao1, SUN Lixing1,2, ZHANG Zhe1, WANG Yuxuan1
- 作者单位:
- 1. 西安理工大学 材料科学与工程学院 陕西省电工材料与熔(浸)渗技术重点实验室 导电材料与复合技术教育部工程研究中心,陕西 西安 710048; 2. 西安智通自动化技术开发公司,陕西 西安 710048
1. Engineering Research Center of Conducting Materials and Composite Technology, Ministry of Education, Shaanxi Key Laboratory of Electrical Materials and Infiltration Technology, School of Materials Science and Engineering, Xi'an University of Technology, Xi'an 710048, China; 2. Xi'an Zhitong Automation Technology Development Company, Xi'an 710048, China
- 关键词:
- Cu-15Sn-0.3Ti合金;电弧熔炼;热挤压;微观组织;力学性能
Cu-15Sn-0.3Ti alloy; arc melting; hot extrusion; microstructure; mechanical properties
- 摘要:
CuSnTi合金是青铜法制备Nb3Sn超导线材的关键材料,常规铸造法制备的CuSnTi合金晶粒粗大,反偏析现象严重,无法满足制备Nb3Sn线材高伸长率的要求。本研究采用热-力协同强化的思路,通过调控电弧熔炼及热挤压工艺参数,使Cu-15Sn-0.3Ti合金发生再结晶行为,成功制备出组织为细小等轴晶,力学性能良好的高溶质Cu-15Sn-0.3Ti合金。结果表明,在热-力协同作用下,铸态Cu-15Sn-0.3Ti合金中粗大的树枝晶演化为细小的等轴晶,存在于枝晶间隙的富锡相发生回溶,合金组织转变为单一的α相;合金的极限抗拉强度达到387.2 MPa,伸长率达到42.5%,强度与伸长率超过了进口铜锡合金的性能指标。
A CuSnTi alloy is the key material for the preparation of Nb3Sn superconducting wires by the bronze method. Coarse grains and anti-segregation occurred in the Cu-15Sn-0.3Ti alloy prepared by conventional casting, which cannot meet the requirements of high elongation of Nb3Sn wires. In this work, the recrystallization of a Cu-15Sn-0.3Ti alloy was successfully induced by adjusting the process parameters of arc melting and hot extrusion composite processes, and a high-Sn content Cu-15Sn-0.3Ti alloy with fine equiaxed grains and good mechanical properties was prepared by using the idea of thermal-mechanical synergistic strengthening. The results show that under thermal-mechanical synergy, the coarse dendrites in the as-cast Cu-15Sn-0.3Ti alloy evolve into fine equiaxed crystals, the tin-rich phase in the dendrite gap dissolves, and the microstructure of the alloy transforms into a single α phase. The ultimate tensile strength of the alloy reaches 387.2 MPa, and the elongation reaches 42.5%, which exceeds the performance indices of imported CuSn alloys.