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熔体冷速对高铁含量 A356 铝合金中富铁相尺寸及类型的影响
Effect of the Molten Metal Cooling Rate on the Size and Type ofIron-rich Phases in High Iron Containing A356 Al Alloys
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- DOI:
- 作者:
- 牛云霞 1,张丽芝 1,万 杰 1,刘海峰 2,陈豫增 1,3,4
NIU Yunxia1, ZHANG Lizhi1, WAN Jie1, LIU Haifeng2, CHEN Yuzeng1,3,4
- 作者单位:
- 1. 西北工业大学 凝固技术全国重点实验室,陕西 西安 710072;2. 中信戴卡股份有限公司,河北 秦皇岛 066011;3. 西北工业大学宁波研究院,浙江 宁波 315103;4. 苏州匀晶金属科技有限公司,江苏 苏州 215024
1. State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi'an 710072, China; 2. ChinaInternational Trust and Investment Corporation Dicastal Co., Ltd., Qinhuangdao 066011, China; 3. Ningbo Institute ofNorthwestern Polytechnical University, Ningbo 315103, China; 4. Suzhou Yunjing Metal Technology Co., Ltd., Suzhou215024, China
- 关键词:
- 高铁含量 A356 铝合金;富铁相;熔体冷速;微观组织
high-Fe-containing A356 Al alloy; iron-rich phases; cooling rate; microstructure
- 摘要:
- 原铝生产面临严峻的环境与能源压力,回收利用 A356 铝合金废料兼具显著的环保和经济价值。 然而,废铝再生过程铁元素易过量积累,较低熔体冷速下会形成粗大脆性富铁相,恶化合金力学性能。 本研究通过提高熔体冷速优化富铁相的形貌与组成,以铁含量为 0.36%(质量分数)的 A356 铝合金为研究对象,采用不同尺寸的铜模调控熔体冷速(15~108 K/s),对比研究各熔体冷速下富铁相的形貌、尺寸及分布规律。 结果表明,随着熔体冷速的提高,富铁相显著细化,分布更趋均匀。 相组成分析进一步表明,提高熔体冷速(72~108 K/s)有效抑制了粗大有害相 β-Fe 的析出,转而促进形成更为细小、对基体割裂作用较弱的 π-Fe 相。The primary Al production industry poses significant environmental and energy challenges, making the recyclingof A356 Al alloy scrap highly attractive from both ecological and economic perspectives. A critical issue in recycling is theinevitable accumulation of Fe, which leads to the formation of coarse, brittle iron-rich intermetallics at lower solidificationcooling rates, severely degrading the mechanical properties. On this basis, the role of increased cooling rates in modifyingthe morphology and composition of these iron-rich phases was investigated. Using a copper mold technique to achieve arange of cooling rates (15~108 K/s), their impact on the microstructure of an A356 Al alloy containing 0.36 wt.% Fe wassystematically examined. The results demonstrate that higher cooling rates significantly refine the iron-rich phases andpromote a more uniform distribution. Phase analysis further revealed that at elevated cooling rates (72~108 K/s), theprecipitation of the detrimental β-Fe phase is suppressed, favouring the formation of the less harmful π-Fe phase.












